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| BGL BNP PARIBAS Luxembourg Open | ||
| Surface: Hard | Date: Oct. 14 - Oct. 20 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Timea Bacsinszky | Win | 6-3, 6-3 |
| Second Round | Yvonne Meusburger | Win | 7-5, 6-4 |
| Quarterfinals | Stefanie Voegele | Loss | 3-6, 6-3, 2-6 |
| Generali Ladies Linz | ||
| Surface: Hard | Date: Oct. 7 - Oct. 13 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Magdalena Rybarikova | Win | 6-3, 6-1 |
| Second Round | Andrea Petkovic | Win | 7-6 (7-1), 4-6, 6-3 |
| Quarterfinals | Stefanie Voegele | Loss | 7-6 (7-3), 4-6, 5-7 |
| China Open | ||
| Surface: Hard | Date: Sep. 27 - Oct. 6 | Seed: 11 |
| Round | Opponent | W / L | Result |
| First Round | Aleksandra Wozniak | Win | 6-4, 6-4 |
| Second Round | Eugenie Bouchard | Win | 6-1, 1-6, 6-4 |
| Third Round | Caroline Wozniacki | Loss | 3-6, 1-6 |
| Toray Pan Pacific Open | ||
| Surface: Hard | Date: Sep. 21 - Sep. 28 | Seed: 9 |
| Round | Opponent | W / L | Result |
| First Round | Stefanie Voegele | Win | 6-3, 6-2 |
| Second Round | Eugenie Bouchard | Loss | 7-5, 6-7 (7-9), 3-6 |
| US Open | ||
| Surface: Hard | Date: Aug. 26 - Sep. 9 | Seed: 15 |
| Round | Opponent | W / L | Result |
| First Round | Mandy Minella | Win | 4-6, 6-3, 7-6 (7-5) |
| Second Round | Urszula Radwanska | Win | 6-1, 6-1 |
| Third Round | Jamie Hampton | Win | 6-1, 6-3 |
| Fourth Round | Serena Williams | Loss | 4-6, 1-6 |
| New Haven Open at Yale | ||
| Surface: Hard | Date: Aug. 18 - Aug. 24 | Seed: 6 |
| Round | Opponent | W / L | Result |
| First Round | Anna Karolina Schmiedlova | Win | 6-4, 6-4 |
| Second Round | Julia Goerges | Win | 7-5, 2-6, 6-1 |
| Quarterfinals | Caroline Wozniacki | Loss | 6-7 (6-8), 2-6 |
| Western & Southern Open | ||
| Surface: Hard | Date: Aug. 11 - Aug. 18 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Petra Martic | Win | 6-2, 3-6, 6-3 |
| Second Round | Maria Sharapova | Win | 2-6, 7-6 (7-5), 6-3 |
| Third Round | Jelena Jankovic | Loss | 6-3, 5-7, 5-7 |
| Rogers Cup | ||
| Surface: Hard | Date: Aug. 5 - Aug. 11 | Seed: 14 |
| Round | Opponent | W / L | Result |
| First Round | Kristina Mladenovic | Win | 6-2, 7-6 (7-5) |
| Second Round | Mona Barthel | Win | 6-3, 4-6, 6-3 |
| Third Round | Agnieszka Radwanska | Loss | 1-6, 6-7 (2-7) |
| Citi Open | ||
| Surface: Hard | Date: Jul. 29 - Aug. 4 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Olga Puchkova | Loss | 5-7, 3-6 |
| Wimbledon | ||
| Surface: Grass | Date: Jun. 24 - Jul. 7 | Seed: 17 |
| Round | Opponent | W / L | Result |
| First Round | Jamie Hampton | Win | 6-3, 6-3 |
| Second Round | Andrea Petkovic | Win | 7-6 (7-2), 2-6, 8-6 |
| Third Round | Petra Cetkovska | Win | 7-6 (7-3), 0-6, 6-4 |
| Fourth Round | Monica Puig | Win | 4-6, 7-5, 6-1 |
| Quarterfinals | Marion Bartoli | Loss | 4-6, 5-7 |
| Roland Garros | ||
| Surface: Red Clay | Date: May 26 - Jun. 9 | Seed: 17 |
| Round | Opponent | W / L | Result |
| First Round | Karin Knapp | Win | 6-2, 7-5 |
| Second Round | Vania King | Win | 6-1, 6-3 |
| Third Round | Marina Erakovic | Win | 6-4, 6-7 (5-7), 6-3 |
| Fourth Round | Maria Sharapova | Loss | 4-6, 3-6 |
| Brussels Open | ||
| Surface: Red Clay | Date: May 20 - May 25 | Seed: 4 |
| Round | Opponent | W / L | Result |
| First Round | Tsvetana Pironkova | Win | 6-3, 2-6, 6-3 |
| Second Round | Shuai Zhang | Win | 6-4, 6-0 |
| Quarterfinals | Shuai Peng | Loss | 2-6, 3-6 |
| Internazionali BNL d'Italia | ||
| Surface: Red Clay | Date: May 12 - May 19 | Seed: 16 |
| Round | Opponent | W / L | Result |
| First Round | Flavia Pennetta | Win | 6-3, 6-3 |
| Second Round | Kiki Bertens | Win | 4-6, 6-3, 6-2 |
| Third Round | Maria Sharapova | Loss | 2-6, 1-6 |
| Mutua Madrid Open | ||
| Surface: Red Clay | Date: May 4 - May 12 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Daniela Hantuchova | Loss | 3-6, 5-7 |
| Family Circle Cup | ||
| Surface: Green Clay | Date: Apr. 1 - Apr. 7 | Seed: 4 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Bethanie Mattek-Sands | Loss | 2-6, 0-6 |
| Sony Open Tennis | ||
| Surface: Hard | Date: Mar. 19 - Mar. 31 | Seed: 16 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Olga Govortsova | Win | 0-6, 6-4, 6-4 |
| Third Round | Venus Williams | Win | Retired |
| Fourth Round | Agnieszka Radwanska | Loss | 6-4, 2-6, 0-6 |
| BNP Paribas Open | ||
| Surface: Hard | Date: Mar. 6 - Mar. 17 | Seed: 15 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Urszula Radwanska | Loss | 3-6, 4-6 |
| Dubai Duty Free Tennis Championships | ||
| Surface: Hard | Date: Feb. 18 - Feb. 23 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Sorana Cirstea | Loss | 7-5, 3-6, 2-6 |
| Qatar Total Open | ||
| Surface: Hard | Date: Feb. 11 - Feb. 17 | Seed: 16 |
| Round | Opponent | W / L | Result |
| First Round | Anna Tatishvili | Win | 6-2, 6-2 |
| Second Round | Klara Zakopalova | Loss | 6-4, 6-7 (5-7), 6-7 (5-7) |
| Australian Open | ||
| Surface: Hard | Date: Jan. 13 - Jan. 27 | Seed: 29 |
| Round | Opponent | W / L | Result |
| First Round | Simona Halep | Win | 6-1, 6-1 |
| Second Round | Kristina Mladenovic | Win | 6-4, 6-3 |
| Third Round | Laura Robson | Win | 7-5, 6-3 |
| Fourth Round | Bojana Jovanovski | Win | 6-1, 3-6, 7-5 |
| Quarterfinals | Serena Williams | Win | 3-6, 7-5, 6-4 |
| Semifinals | Victoria Azarenka | Loss | 1-6, 4-6 |
| Moorilla Hobart International | ||
| Surface: Hard | Date: Jan. 5 - Jan. 12 | Seed: 8 |
| Round | Opponent | W / L | Result |
| First Round | Laura Robson | Win | 6-4, 7-6 (7-4) |
| Second Round | Simona Halep | Win | 6-4, 6-0 |
| Quarterfinals | Lauren Davis | Win | 6-3, 4-6, 7-5 |
| Semifinals | Elena Vesnina | Loss | 2-6, 2-6 |
| Brisbane International | ||
| Surface: Hard | Date: Dec. 29 - Jan. 6 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Dominika Cibulkova | Win | 6-2, 6-3 |
| Second Round | Sofia Arvidsson | Win | 6-3, 6-4 |
| Quarterfinals | Serena Williams | Loss | 4-6, 3-6 |
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