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| TEB BNP PARIBAS WTA Championships | ||
| Surface: Hard | Date: Oct. 22 - Oct. 27 | Seed: 2 |
| Round | Opponent | W / L | Result |
| Round Robin | Sara Errani | Win | 7-6 (7-4), 6-2 4-6, 3-6 2-6, 1-6 |
| Round Robin | Jelena Jankovic | Loss | 7-6 (7-4), 6-2 4-6, 3-6 2-6, 1-6 |
| Round Robin | Na Li | Loss | 7-6 (7-4), 6-2 4-6, 3-6 2-6, 1-6 |
| China Open | ||
| Surface: Hard | Date: Sep. 27 - Oct. 6 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Andrea Petkovic | Loss | 4-6, 6-2, 4-6 |
| Toray Pan Pacific Open | ||
| Surface: Hard | Date: Sep. 21 - Sep. 28 | Seed: 1 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Venus Williams | Loss | 2-6, 4-6 |
| US Open | ||
| Surface: Hard | Date: Aug. 26 - Sep. 9 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Dinah Pfizenmaier | Win | 6-0, 6-0 |
| Second Round | Aleksandra Wozniak | Win | 6-3, 6-1 |
| Third Round | Alize Cornet | Win | 6-7 (2-7), 6-3, 6-2 |
| Fourth Round | Ana Ivanovic | Win | 4-6, 6-3, 6-4 |
| Quarterfinals | Daniela Hantuchova | Win | 6-2, 6-3 |
| Semifinals | Flavia Pennetta | Win | 6-4, 6-2 |
| Final | Serena Williams | Loss | 5-7, 7-6 (8-6), 1-6 |
| Western & Southern Open | ||
| Surface: Hard | Date: Aug. 11 - Aug. 18 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Vania King | Win | 6-1, 7-6 (8-6) |
| Third Round | Magdalena Rybarikova | Win | 6-3, 6-4 |
| Quarterfinals | Caroline Wozniacki | Win | 6-3, 7-6 (7-5) |
| Semifinals | Jelena Jankovic | Win | 4-6, 6-2, 6-3 |
| Final | Serena Williams | Win | 2-6, 6-2, 7-6 (8-6) |
| Southern California Open | ||
| Surface: Hard | Date: Jul. 29 - Aug. 4 | Seed: 1 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Francesca Schiavone | Win | 6-2, 6-3 |
| Quarterfinals | Urszula Radwanska | Win | 6-1, 6-2 |
| Semifinals | Ana Ivanovic | Win | 6-0, 4-6, 6-3 |
| Final | Samantha Stosur | Loss | 2-6, 2-6 |
| Wimbledon | ||
| Surface: Grass | Date: Jun. 24 - Jul. 7 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Maria Joao Koehler | Win | 6-1, 6-2 |
| Second Round | Flavia Pennetta | Loss | 0-0 Retired |
| Roland Garros | ||
| Surface: Red Clay | Date: May 26 - Jun. 9 | Seed: 3 |
| Round | Opponent | W / L | Result |
| First Round | Elena Vesnina | Win | 6-1, 6-4 |
| Second Round | Annika Beck | Win | 6-4, 6-3 |
| Third Round | Alize Cornet | Win | 4-6, 6-3, 6-1 |
| Fourth Round | Francesca Schiavone | Win | 6-3, 6-0 |
| Quarterfinals | Maria Kirilenko | Win | 7-6 (7-3), 6-2 |
| Semifinals | Maria Sharapova | Loss | 1-6, 6-2, 4-6 |
| Internazionali BNL d'Italia | ||
| Surface: Red Clay | Date: May 12 - May 19 | Seed: 3 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Julia Goerges | Win | 6-2, 6-0 |
| Third Round | Ayumi Morita | Win | 6-1, 2-0 Retired |
| Quarterfinals | Samantha Stosur | Win | 6-4, 1-6, 6-3 |
| Semifinals | Sara Errani | Win | 6-0, 7-5 |
| Final | Serena Williams | Loss | 1-6, 3-6 |
| Mutua Madrid Open | ||
| Surface: Red Clay | Date: May 4 - May 12 | Seed: 3 |
| Round | Opponent | W / L | Result |
| First Round | Anastasia Pavlyuchenkova | Win | 7-6 (10-8), 7-6 (7-3) |
| Second Round | Ekaterina Makarova | Loss | 6-1, 2-6, 3-6 |
| BNP Paribas Open | ||
| Surface: Hard | Date: Mar. 6 - Mar. 17 | Seed: 1 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Daniela Hantuchova | Win | 6-4, 6-1 |
| Third Round | Kirsten Flipkens | Win | 3-6, 6-3, 6-0 |
| Fourth Round | Urszula Radwanska | Win | 6-3, 6-1 |
| Quarterfinals | Caroline Wozniacki | Loss | Retired |
| Qatar Total Open | ||
| Surface: Hard | Date: Feb. 11 - Feb. 17 | Seed: 1 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Romina Oprandi | Win | 6-2, 6-3 |
| Third Round | Christina McHale | Win | 6-0, 6-0 |
| Quarterfinals | Sara Errani | Win | 6-2, 6-2 |
| Semifinals | Agnieszka Radwanska | Win | 6-3, 6-3 |
| Final | Serena Williams | Win | 7-6 (8-6), 2-6, 6-3 |
| Australian Open | ||
| Surface: Hard | Date: Jan. 13 - Jan. 27 | Seed: 1 |
| Round | Opponent | W / L | Result |
| First Round | Monica Niculescu | Win | 6-1, 6-4 |
| Second Round | Eleni Daniilidou | Win | 6-1, 6-0 |
| Third Round | Jamie Hampton | Win | 6-4, 4-6, 6-2 |
| Fourth Round | Elena Vesnina | Win | 6-1, 6-1 |
| Quarterfinals | Svetlana Kuznetsova | Win | 7-5, 6-1 |
| Semifinals | Sloane Stephens | Win | 6-1, 6-4 |
| Final | Na Li | Win | 4-6, 6-4, 6-3 |
| Brisbane International | ||
| Surface: Hard | Date: Dec. 29 - Jan. 6 | Seed: 1 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Sabine Lisicki | Win | 6-3, 6-3 |
| Quarterfinals | Ksenia Pervak | Win | 6-1, 6-0 |
| Semifinals | Serena Williams | Loss | Retired |
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