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| Barclays ATP World Tour Finals | ||
| Surface: Hard | Date: Nov. 4 - Nov. 11 | Seed: 7 |
| Round | Opponent | W / L | Result |
| Round Robin | Tomas Berdych | Win | 6-3, 6-7 (0-7), 6-3 6-7 (5-7), 6-7 (6-8) 6-7 (3-7), 6-4, 6-1 |
| Round Robin | Rafael Nadal | Loss | 6-3, 6-7 (0-7), 6-3 6-7 (5-7), 6-7 (6-8) 6-7 (3-7), 6-4, 6-1 |
| Round Robin | David Ferrer | Win | 6-3, 6-7 (0-7), 6-3 6-7 (5-7), 6-7 (6-8) 6-7 (3-7), 6-4, 6-1 |
| Semifinals | Novak Djokovic | Loss | 3-6, 3-6 |
| BNP Paribas Masters | ||
| Surface: Hard | Date: Oct. 28 - Nov. 3 | Seed: 7 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Feliciano Lopez | Win | 6-3, 3-6, 6-3 |
| Third Round | Nicolas Almagro | Win | 6-3, 6-2 |
| Quarterfinals | Novak Djokovic | Loss | 1-6, 4-6 |
| Swiss Indoors Basel | ||
| Surface: Hard | Date: Oct. 21 - Oct. 27 | Seed: 4 |
| Round | Opponent | W / L | Result |
| First Round | Edouard Roger-Vasselin | Loss | 4-6, 3-6 |
| Shanghai Rolex Masters | ||
| Surface: Hard | Date: Oct. 6 - Oct. 13 | Seed: 8 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Kevin Anderson | Win | 6-4, 3-6, 7-6 (8-6) |
| Third Round | Milos Raonic | Win | 7-6 (7-2), 6-4 |
| Quarterfinals | Rafael Nadal | Loss | 6-7 (10-12), 1-6 |
| China Open | ||
| Surface: Hard | Date: Sep. 27 - Oct. 6 | Seed: 6 |
| Round | Opponent | W / L | Result |
| First Round | Andreas Seppi | Win | 4-6, 6-3, 6-4 |
| Second Round | Sam Querrey | Loss | 3-6, 6-7 (2-7) |
| Malaysian Open | ||
| Surface: Hard | Date: Sep. 22 - Sep. 29 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Marcos Baghdatis | Win | 6-1, 7-5 |
| Quarterfinals | Dmitry Tursunov | Win | 2-6, 6-3, 7-6 (7-3) |
| Semifinals | Julien Benneteau | Loss | 4-6, 3-6 |
| US Open | ||
| Surface: Hard | Date: Aug. 26 - Sep. 9 | Seed: 9 |
| Round | Opponent | W / L | Result |
| First Round | Radek Stepanek | Win | 7-6 (7-2), 6-3, 6-2 |
| Second Round | Ivo Karlovic | Win | 7-5, 7-6 (10-8), 6-4 |
| Third Round | Marcos Baghdatis | Win | 6-3, 6-2, 6-7 (1-7), 7-6(9-7) |
| Fourth Round | Tomas Berdych | Win | 3-6, 6-1, 7-6 (8-6), 6-2 |
| Quarterfinals | Andy Murray | Win | 6-4, 6-3, 6-2 |
| Semifinals | Novak Djokovic | Loss | 6-2, 6-7 (4-7), 6-3, 3-6, 4-6 |
| Western & Southern Open | ||
| Surface: Hard | Date: Aug. 11 - Aug. 18 | Seed: 9 |
| Round | Opponent | W / L | Result |
| First Round | Andreas Seppi | Win | 6-3, 6-4 |
| Second Round | Tommy Robredo | Loss | 5-7, 6-3, 3-6 |
| Rogers Cup | ||
| Surface: Hard | Date: Aug. 5 - Aug. 11 | Seed: 8 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Benoit Paire | Loss | 2-6, 6-7 (2-7) |
| Credit Agricole Suisse Open Gstaad | ||
| Surface: Clay | Date: Jul. 22 - Jul. 28 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Daniel Gimeno-Traver | Win | 7-5, 7-6 (7-4) |
| Quarterfinals | Feliciano Lopez | Loss | 4-6, 6-2, 3-4 Retired |
| Wimbledon | ||
| Surface: Grass | Date: Jun. 24 - Jul. 7 | Seed: 11 |
| Round | Opponent | W / L | Result |
| First Round | Lleyton Hewitt | Loss | 4-6, 5-7, 3-6 |
| Topshelf Open | ||
| Surface: Grass | Date: Jun. 16 - Jun. 22 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Steve Darcis | Win | 7-6 (7-5), 6-4 |
| Second Round | Paolo Lorenzi | Win | 6-3, 7-6 (10-8) |
| Quarterfinals | Jeremy Chardy | Win | 6-4, 7-6 (7-2) |
| Semifinals | Guillermo Garcia-Lopez | Win | 6-1, 6-4 |
| Final | Nicolas Mahut | Loss | 3-6, 4-6 |
| Roland Garros | ||
| Surface: Red Clay | Date: May 26 - Jun. 9 | Seed: 9 |
| Round | Opponent | W / L | Result |
| First Round | Thiemo De Bakker | Win | 7-5, 6-3, 6-7 (1-7), 7-5 |
| Second Round | Horacio Zeballos | Win | 6-2, 7-6 (7-2), 6-4 |
| Third Round | Jerzy Janowicz | Win | 6-3, 6-7 (2-7), 6-3, 6-3 |
| Fourth Round | Richard Gasquet | Win | 6-7 (5-7), 4-6, 6-4, 7-5, 8-6 |
| Quarterfinals | Rafael Nadal | Loss | 2-6, 3-6, 1-6 |
| Internazionali BNL d'Italia | ||
| Surface: Red Clay | Date: May 12 - May 19 | Seed: 15 |
| Round | Opponent | W / L | Result |
| First Round | Carlos Berlocq | Win | 5-7, 6-3, 6-3 |
| Second Round | Alexandr Dolgopolov | Loss | Retired |
| Mutua Madrid Open | ||
| Surface: Red Clay | Date: May 4 - May 12 | Seed: 15 |
| Round | Opponent | W / L | Result |
| First Round | Marius Copil | Win | 6-4, 6-4 |
| Second Round | Santiago Giraldo | Win | 6-3, 6-3 |
| Third Round | Grigor Dimitrov | Win | 3-6, 6-4, 6-1 |
| Quarterfinals | Jo-Wilfried Tsonga | Win | 6-2, 6-7 (9-11), 6-4 |
| Semifinals | Tomas Berdych | Win | 6-3, 4-6, 6-4 |
| Final | Rafael Nadal | Loss | 2-6, 4-6 |
| Portugal Open | ||
| Surface: Red Clay | Date: Apr. 29 - May 5 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Albert Ramos | Win | 1-6, 6-3, 6-4 |
| Quarterfinals | Gastao Elias | Win | 6-4, 6-4 |
| Semifinals | Pablo Carreno-Busta | Win | 6-3, 3-6, 6-1 |
| Final | David Ferrer | Win | 6-1, 6-4 |
| Monte-Carlo Rolex Masters | ||
| Surface: Clay | Date: Apr. 14 - Apr. 21 | Seed: 13 |
| Round | Opponent | W / L | Result |
| First Round | Denis Istomin | Win | 6-3, 7-5 |
| Second Round | Albert Montanes | Win | 6-1, 6-1 |
| Third Round | Andy Murray | Win | 6-1, 6-2 |
| Quarterfinals | Jo-Wilfried Tsonga | Loss | 6-2, 3-6, 4-6 |
| Grand Prix Hassan II | ||
| Surface: Red Clay | Date: Apr. 8 - Apr. 14 | Seed: 1 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Blaz Kavcic | Win | 4-6, 6-2, 6-1 |
| Quarterfinals | Guillermo Garcia-Lopez | Win | 6-1, 6-2 |
| Semifinals | Tommy Robredo | Loss | 6-1, 3-6, 2-6 |
| BNP Paribas Open | ||
| Surface: Hard | Date: Mar. 6 - Mar. 17 | Seed: 18 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Wayne Odesnik | Win | 3-6, 6-2, 6-1 |
| Third Round | Lleyton Hewitt | Win | 6-4, 7-5 |
| Fourth Round | Roger Federer | Loss | 3-6, 7-6 (7-4), 5-7 |
| Abierto Mexicano Telcel | ||
| Surface: Red Clay | Date: Feb. 25 - Mar. 2 | Seed: 4 |
| Round | Opponent | W / L | Result |
| First Round | Fabio Fognini | Loss | 2-6, 6-7 (3-7) |
| Copa Claro | ||
| Surface: Clay | Date: Feb. 18 - Feb. 24 | Seed: 3 |
| Round | Opponent | W / L | Result |
| First Round | Paolo Lorenzi | Win | 6-3, 6-3 |
| Second Round | Daniel Gimeno-Traver | Win | 6-1, 6-4 |
| Quarterfinals | Albert Ramos | Win | 7-6 (7-4), 6-4 |
| Semifinals | Nicolas Almagro | Win | 6-3, 7-5 |
| Final | David Ferrer | Loss | 4-6, 6-3, 1-6 |
| Australian Open | ||
| Surface: Hard | Date: Jan. 13 - Jan. 27 | Seed: 15 |
| Round | Opponent | W / L | Result |
| First Round | Cedrik-Marcel Stebe | Win | 6-2, 6-4, 6-3 |
| Second Round | Tobias Kamke | Win | 6-3, 7-6 (7-4), 0-0 Retired |
| Third Round | Sam Querrey | Win | 7-6 (8-6), 7-5, 6-4 |
| Fourth Round | Novak Djokovic | Loss | 6-1, 5-7, 4-6, 7-6 (7-5), 10-12 |
| Aircel Chennai Open | ||
| Surface: Hard | Date: Dec. 31 - Jan. 6 | Seed: 4 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Cedrik-Marcel Stebe | Win | 6-4, 6-3 |
| Quarterfinals | Aljaz Bedene | Loss | 2-6, 6-7 (6-8) |
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