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| BNP Paribas Masters | ||
| Surface: Hard | Date: Oct. 28 - Nov. 3 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Andreas Seppi | Win | 6-3, 3-6, 6-4 |
| Second Round | Tommy Haas | Win | 6-2, 6-2 |
| Third Round | Roger Federer | Loss | 3-6, 4-6 |
| Valencia Open 500 | ||
| Surface: Hard | Date: Oct. 21 - Oct. 27 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Tommy Haas | Win | 3-6, 6-3, 6-3 |
| Second Round | Mikhail Youzhny | Loss | 4-6, 3-6 |
| Erste Bank Open | ||
| Surface: Hard | Date: Oct. 14 - Oct. 20 | Seed: 4 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Ruben Bemelmans | Loss | 6-4, 1-6, 6-7 (0-7) |
| Shanghai Rolex Masters | ||
| Surface: Hard | Date: Oct. 6 - Oct. 13 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Maoxin Gong | Win | 7-5, 6-2 |
| Second Round | Juan Martin del Potro | Loss | 6-3, 3-6, 6-7 (4-7) |
| China Open | ||
| Surface: Hard | Date: Sep. 27 - Oct. 6 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Albert Montanes | Win | 7-5, 1-6, 7-6 (7-4) |
| Second Round | Rafael Nadal | Loss | 4-6, 6-7 (3-7) |
| Open de Moselle | ||
| Surface: Hard | Date: Sep. 16 - Sep. 22 | Seed: 4 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Carlos Berlocq | Loss | 7-6 (9-7), 6-7 (5-7), 1-2 Retired |
| US Open | ||
| Surface: Hard | Date: Aug. 26 - Sep. 9 | Seed: 22 |
| Round | Opponent | W / L | Result |
| First Round | Collin Altamirano | Win | 6-1, 6-3, 6-1 |
| Second Round | Edouard Roger-Vasselin | Win | 6-3, 6-2, 5-7, 6-2 |
| Third Round | John Isner | Win | 6-4, 3-6, 7-5, 7-6(7-5) |
| Fourth Round | Rafael Nadal | Loss | 7-6 (7-4), 4-6, 3-6, 1-6 |
| Western & Southern Open | ||
| Surface: Hard | Date: Aug. 11 - Aug. 18 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Mardy Fish | Win | 7-5, 6-2 |
| Second Round | Roger Federer | Loss | 3-6, 6-7 (7-9) |
| Rogers Cup | ||
| Surface: Hard | Date: Aug. 5 - Aug. 11 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Benoit Paire | Loss | 6-7 (1-7), 5-7 |
| bet-at-home Cup Kitzbuhel | ||
| Surface: Clay | Date: Jul. 28 - Aug. 3 | Seed: 1 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Leonardo Mayer | Loss | 4-6, 6-7 (4-7) |
| MercedesCup | ||
| Surface: Clay | Date: Jul. 8 - Jul. 14 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Nils Langer | Win | 7-5, 6-2 |
| Quarterfinals | Gael Monfils | Win | 6-4, 6-4 |
| Semifinals | Victor Hanescu | Win | 6-3, 6-3 |
| Final | Fabio Fognini | Loss | 7-5, 4-6, 4-6 |
| Wimbledon | ||
| Surface: Grass | Date: Jun. 24 - Jul. 7 | Seed: 16 |
| Round | Opponent | W / L | Result |
| First Round | Ivan Dodig | Loss | 6-4, 7-6 (8-6), 6-7 (3-7), 3-6, 1-2 Retired |
| AEGON International | ||
| Surface: Grass | Date: Jun. 17 - Jun. 22 | Seed: 3 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Radek Stepanek | Loss | 5-7, 3-6 |
| Gerry Weber Open | ||
| Surface: Grass | Date: Jun. 10 - Jun. 16 | Seed: 6 |
| Round | Opponent | W / L | Result |
| First Round | Carlos Berlocq | Win | 6-3, 6-1 |
| Second Round | Tobias Kamke | Win | 6-4, 6-3 |
| Quarterfinals | Mikhail Youzhny | Loss | 3-6, 2-6 |
| Roland Garros | ||
| Surface: Red Clay | Date: May 26 - Jun. 9 | Seed: 16 |
| Round | Opponent | W / L | Result |
| First Round | Jiri Vesely | Win | 7-6 (7-3), 6-1, 5-7, 6-2 |
| Second Round | Yen-Hsun Lu | Win | Retired |
| Third Round | Victor Hanescu | Win | 6-0, 7-6 (7-0), 6-1 |
| Fourth Round | Novak Djokovic | Loss | 6-4, 3-6, 4-6, 4-6 |
| Power Horse Cup | ||
| Surface: Clay | Date: May 19 - May 25 | Seed: 4 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Igor Sijsling | Loss | 6-3, 3-6, 4-6 |
| Internazionali BNL d'Italia | ||
| Surface: Red Clay | Date: May 12 - May 19 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Milos Raonic | Win | 7-6 (7-2), 6-4 |
| Second Round | Albert Ramos | Win | 6-4, 6-1 |
| Third Round | David Ferrer | Loss | Retired |
| BMW Open | ||
| Surface: Red Clay | Date: Apr. 29 - May 5 | Seed: 4 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Evgeny Korolev | Win | 6-2, 6-4 |
| Quarterfinals | Viktor Troicki | Win | 6-3, 7-6 (7-3) |
| Semifinals | Daniel Brands | Win | 6-7 (4-7), 6-3, 7-6 (7-5) |
| Final | Tommy Haas | Loss | 3-6, 6-7 (3-7) |
| Barcelona Open Banc Sabadell | ||
| Surface: Clay | Date: Apr. 22 - Apr. 28 | Seed: 8 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Andrey Kuznetsov | Win | 6-3, 6-7 (5-7), 7-6 (7-2) |
| Third Round | Martin Klizan | Win | 1-6, 7-6 (7-2), 7-6 (7-5) |
| Quarterfinals | Thomaz Bellucci | Win | Retired |
| Semifinals | Nicolas Almagro | Loss | 2-6, 1-6 |
| Monte-Carlo Rolex Masters | ||
| Surface: Clay | Date: Apr. 14 - Apr. 21 | Seed: 16 |
| Round | Opponent | W / L | Result |
| First Round | Thomaz Bellucci | Win | 6-4, 6-2 |
| Second Round | Pablo Andujar | Win | 6-2, 2-6, 7-6 (7-3) |
| Third Round | Rafael Nadal | Loss | 2-6, 4-6 |
| Sony Open Tennis | ||
| Surface: Hard | Date: Mar. 19 - Mar. 31 | Seed: 18 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | David Goffin | Loss | 6-7 (5-7), 6-4, 2-6 |
| BNP Paribas Open | ||
| Surface: Hard | Date: Mar. 6 - Mar. 17 | Seed: 21 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Benoit Paire | Loss | 4-6, 2-6 |
| Australian Open | ||
| Surface: Hard | Date: Jan. 13 - Jan. 27 | Seed: 17 |
| Round | Opponent | W / L | Result |
| First Round | Steve Darcis | Win | 6-2, 6-3, 6-4 |
| Second Round | Amir Weintraub | Win | 6-2, 7-6 (7-4), 6-4 |
| Third Round | Milos Raonic | Loss | 6-7 (4-7), 3-6, 4-6 |
| Heineken Open | ||
| Surface: Hard | Date: Jan. 6 - Jan. 12 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Alejandro Falla | Win | 7-6 (7-4), 4-6, 6-3 |
| Quarterfinals | Xavier Malisse | Win | 7-6 (8-6), 6-4 |
| Semifinals | Sam Querrey | Win | 6-4, 7-6 (7-2) |
| Final | David Ferrer | Loss | 6-7 (5-7), 1-6 |
| Qatar ExxonMobil Open | ||
| Surface: Hard | Date: Dec. 31 - Jan. 6 | Seed: 3 |
| Round | Opponent | W / L | Result |
| First Round | Ivan Dodig | Win | 7-6 (7-5), 6-1 |
| Second Round | Gael Monfils | Loss | 4-6, 6-2, 4-6 |
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